Three-dimensional mapping and electronic origin of large altermagnetic splitting near Fermi level in CrSb

Recently, a new kind of collinear magnetism, dubbed altermagnetism, has attracted considerable interests. A key characteristic of altermagnet is the momentum-dependent band and spin splitting without net magnetization. However, finding altermagnetic materials with large splitting near the Fermi level, which necessarily requires three-dimensional k-space mapping and is crucial for spintronic applications and emergent phenomena, remains challenging. Here by employing synchrotron-based angle-resolved photoemission spectroscopy (ARPES), spin-resolved ARPES and model calculations, we uncover a large altermagnetic splitting, up to ∼1.0 eV, near the Fermi level in CrSb. We verify its bulk-type g-wave altermagnetism through systematic three-dimensional k-space mapping, which unambiguously reveals the altermagnetic symmetry and associated nodal planes. The ARPES results are well captured by density functional theory calculations. Spin-resolved ARPES measurements further verify the spin polarizations of the split bands near Fermi level. In addition, tight-binding model analysis indicates that the large altermagnetic splitting arises from strong third-nearest-neighbor hopping mediated by Sb ions, which breaks both the space-time reversal symmetry and the translational spin-rotation symmetry. The large band/spin splitting near Fermi level in metallic CrSb, together with its high T_N (up to 705 K) and simple spin configuration, paves the way for exploring emergent phenomena and spintronic applications based on altermagnets.