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Molecular Mechanisms of Enhanced Conductivity in Ionic Liquid Crystals

ORAL

Abstract

Ionic liquid crystal (ILC) electrolytes combine ordered structures with ionic conductivity and show great promise for solid-state energy storage applications. This study examines LiCnTFSI systems, in particular LiC18TFSI, where enhanced conductivity has been linked to favorable structural properties. We explore how layered structures induced by variable alkyl chain lengths influence ion mobility. We explicitly investigate the ion binding process in the solid state through free energy calculations of the ion dissociation pathway.

Presenters

  • Marvin Diaz-Segura

    University of Notre Dame

Authors

  • Marvin Diaz-Segura

    University of Notre Dame

  • Mohsen Farshad

    University of Notre Dame

  • Jiacheng Liu

    University of Notre Dame

  • Andrew S Manning

    University of Notre Dame

  • Lingyu Yang

    University of Notre Dame

  • Govinda Devkota

    University of Notre Dame

  • Sunil P Upadhyay

    University of Notre Dame

  • Jennifer Schaefer

    University of Notre Dame

  • Jonathan K Whitmer

    University of Notre Dame