Surface Engineered Electrodes by Precision Fabrication Approaches for the Application of Energy Storage and Conversion
POSTER
Abstract
In my research, through precise controls over various aspects, we design and obtain advanced electrodes with superior properties, including: high reactivity, exclusive selectivity, and exceptional stability. We demonstrate potential applications of the electrodes in these three important fields. Our work focuses on transition-metal-based electrodes, for which we develop novel designs, through the precise control of crystalline shape, structure, composition, and surface chemistry. Utilizing a range of electrochemical and chemical treatments, we systematically tailor the morphology and composition of different types of transition metal nanomaterials, and achieve enhanced activity while addressing several common challenges, including sluggish reaction kinetics and undesired side reactions. My work opens new possibilities for promising applications in a wide range of fields not limited to energy storage and conversion, but also chemical production and beyond.
Publication: Li, Zhao, Wenhan Niu, Zhenzhong Yang, Abdelkader Kara, Qi Wang, Maoyu Wang, Meng Gu, Zhenxing Feng, Yingge Du, and Yang Yang. "Boosting Alkaline Hydrogen Evolution: The Dominating Role of Interior Modification in Surface Electrocatalysis." Energy & Environmental Science 13, no. 9 (September 16, 2020): 3110–18. https://doi.org/10.1039/D0EE01750G.<br>Li, Zhao, Wenhan Niu, Zhenzhong Yang, Nusaiba Zaman, Widitha Samarakoon, Maoyu Wang, Abdelkader Kara, et al. "Stabilizing Atomic Pt with Trapped Interstitial F in Alloyed PtCo Nanosheets for High-Performance Zinc-Air Batteries." Energy & Environmental Science 13, no. 3 (March 18, 2020): 884–95. https://doi.org/10.1039/C9EE02657F.<br>Li, Zhao, Wenhan Niu, Le Zhou, and Yang Yang. "Phosphorus and Aluminum Codoped Porous NiO Nanosheets as Highly Efficient Electrocatalysts for Overall Water Splitting." ACS Energy Letters 3, no. 4 (April 13, 2018): 892–98. https://doi.org/10.1021/acsenergylett.8b00174.<br>Li, Zhao, Li Shi, Daniel Franklin, Supriya Koul, Akihiro Kushima, and Yang Yang. "Drastic Enhancement of Photoelectrochemical Water Splitting Performance over Plasmonic Al@TiO2 Heterostructured Nanocavity Arrays." Nano Energy 51 (September 1, 2018): 400–407. https://doi.org/10.1016/j.nanoen.2018.06.083.<br>Li, Zhao, Qi Wang, Xiaowan Bai, Maoyu Wang, Zhenzhong Yang, Yingge Du, George E. Sterbinsky, et al. "Doping-Modulated Strain Control of Bifunctional Electrocatalysis for Rechargeable Zinc–Air Batteries." Energy & Environmental Science 14, no. 9 (September 15, 2021): 5035–43. https://doi.org/10.1039/D1EE01271A.<br>Zhang, Wei, Ao Yu, Haiyan Mao, Guangxia Feng, Cheng Li, Guanzhi Wang, Jinfa Chang, et al. "Dynamic Bubbling Balanced Proactive CO2 Capture and Reduction on a Triple-Phase Interface Nanoporous Electrocatalyst." Journal of the American Chemical Society 146, no. 31 (August 7, 2024): 21335–47. https://doi.org/10.1021/jacs.4c02786.<br>Tian, Huajun, Guangxia Feng, Qi Wang, Zhao Li, Wei Zhang, Marcos Lucero, Zhenxing Feng, et al. "Three-Dimensional Zn-Based Alloys for Dendrite-Free Aqueous Zn Battery in Dual-Cation Electrolytes." Nature Communications 13, no. 1 (December 23, 2022): 7922. https://doi.org/10.1038/s41467-022-35618-2.<br>Tian, Huajun, Zhao Li, Guangxia Feng, Zhenzhong Yang, David Fox, Maoyu Wang, Hua Zhou, et al. "Stable, High-Performance, Dendrite-Free, Seawater-Based Aqueous Batteries." Nature Communications 12, no. 1 (January 11, 2021): 237. https://doi.org/10.1038/s41467-020-20334-6.
Presenters
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Zhao Li
University of Central Florida
Authors
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Zhao Li
University of Central Florida