Tunable ultrafast charge transfer across homojunction interface

Charge transfer at heterojunction interfaces is a fundamental process that plays a crucial role in modern electronic and photonic devices. The essence of such charge transfer lies in the band offset, making charge transfer uncommon in homojunction. Recently, sliding ferroelectricity has been proposed and confirmed in two-dimensional van der Waals stacked materials, such as bilayer boron nitride. During the sliding of these layers, the band alignment shifts, creating conditions for charge separation at interface. We employ ab initio nonadiabatic molecular dynamics simulations to elucidate the excited state carrier dynamics in bilayer boron pnictides. We propose that, akin to ferroelectric polarization flipping, the precise modulation of the distribution of excited state carriers can also be reached by sliding. Our results demonstrate that sliding induces a reversal of the frontier orbital distribution on the upper and lower layers, facilitating robust interlayer carrier transfer. Notably, the interlayer carrier transfer is more pronounced in boron phosphide than boron nitride, attributed to strong electron scattering in momentum space in boron nitride. We propose this novel method to manipulate carrier distribution and dynamics in homojunction exhibiting sliding ferroelectricity, in general, paving a new way for developing advanced electronic and photonic devices.