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Carbon Nanotube Aerogels with High Porosity and Electrical Conductivity

ORAL

Abstract

Carbon aerogels are promising materials for energy applications. Freestanding aerogels were created from co-gels of single-wall carbon nanotubes (SWCNT) and the conducting polymer poly(3,4-ethylenedioxythiophene)--poly(styrene sulfonate) (PEDOT:PSS). We tested several ratios of SWCNT/PEDOT:PSS to produce samples with the optimum combination of mechanical and electrical properties. The aerogels are light-weight, mechanically robust, and recover their original shape after deformation. High resolution scanning microscopy analysis shows their high porosity, filamentous structure, and the distribution of the polymer around the SWCNT. We analyzed the electrical properties of the gels using four-point I-V measurements and got high conductivities of over 100 S/cm. We will also present results of the fabrication of these co-gels in the shape of fibers.

Authors

  • Angelo Porcu

    University of Puerto Rico at Humacao

  • Peter Schauss

    University of Notre Dame, Los Alamos National Laboratory, North Carolina State University, University of Notre dame, Columbia University, Mississippi State Univ, University of Pennsylvania, Carnegie Mellon University, University of Puerto Rico at Humacao, JLAB, MIT, University of Alabama at Birmingham, Florida State University, NHMFL, University College Dublin, Department of Physics, Florida State University; National High Magnetic Field Laboratory, CNR-Instituto Nanoscienze, Karlsruhe Institute of Technology (KIT), Institute of Nanotechnology, Department of Chemistry, Florida State University, University of Alabama at Birmingham, Department of Physics, Birmingham, AL 35294-1170,USA, Department of Chemistry, Virginia Polytechnic Institute and State University, Francis Marion University, University of Richmond, Valdosta State University, University of Pittsburgh, Fermi National Lab, university of minnesota, Univ of Virginia, Joint Quantum Institute, University of Maryland, Georgetown University, IonQ Inc.

  • Peter Schauss

    University of Notre Dame, Los Alamos National Laboratory, North Carolina State University, University of Notre dame, Columbia University, Mississippi State Univ, University of Pennsylvania, Carnegie Mellon University, University of Puerto Rico at Humacao, JLAB, MIT, University of Alabama at Birmingham, Florida State University, NHMFL, University College Dublin, Department of Physics, Florida State University; National High Magnetic Field Laboratory, CNR-Instituto Nanoscienze, Karlsruhe Institute of Technology (KIT), Institute of Nanotechnology, Department of Chemistry, Florida State University, University of Alabama at Birmingham, Department of Physics, Birmingham, AL 35294-1170,USA, Department of Chemistry, Virginia Polytechnic Institute and State University, Francis Marion University, University of Richmond, Valdosta State University, University of Pittsburgh, Fermi National Lab, university of minnesota, Univ of Virginia, Joint Quantum Institute, University of Maryland, Georgetown University, IonQ Inc.

  • Idalia Ramos

    University of Puerto Rico at Humacao

  • Peter Schauss

    University of Notre Dame, Los Alamos National Laboratory, North Carolina State University, University of Notre dame, Columbia University, Mississippi State Univ, University of Pennsylvania, Carnegie Mellon University, University of Puerto Rico at Humacao, JLAB, MIT, University of Alabama at Birmingham, Florida State University, NHMFL, University College Dublin, Department of Physics, Florida State University; National High Magnetic Field Laboratory, CNR-Instituto Nanoscienze, Karlsruhe Institute of Technology (KIT), Institute of Nanotechnology, Department of Chemistry, Florida State University, University of Alabama at Birmingham, Department of Physics, Birmingham, AL 35294-1170,USA, Department of Chemistry, Virginia Polytechnic Institute and State University, Francis Marion University, University of Richmond, Valdosta State University, University of Pittsburgh, Fermi National Lab, university of minnesota, Univ of Virginia, Joint Quantum Institute, University of Maryland, Georgetown University, IonQ Inc.

  • Peter Schauss

    University of Notre Dame, Los Alamos National Laboratory, North Carolina State University, University of Notre dame, Columbia University, Mississippi State Univ, University of Pennsylvania, Carnegie Mellon University, University of Puerto Rico at Humacao, JLAB, MIT, University of Alabama at Birmingham, Florida State University, NHMFL, University College Dublin, Department of Physics, Florida State University; National High Magnetic Field Laboratory, CNR-Instituto Nanoscienze, Karlsruhe Institute of Technology (KIT), Institute of Nanotechnology, Department of Chemistry, Florida State University, University of Alabama at Birmingham, Department of Physics, Birmingham, AL 35294-1170,USA, Department of Chemistry, Virginia Polytechnic Institute and State University, Francis Marion University, University of Richmond, Valdosta State University, University of Pittsburgh, Fermi National Lab, university of minnesota, Univ of Virginia, Joint Quantum Institute, University of Maryland, Georgetown University, IonQ Inc.