Excitation-facilitated hops play a dominant role in relaxation and transport of liquids even above T<sub>A</sub>
ORAL
Abstract
It is widely believed that particle hopping is an important mechanism for transport and relaxation in the supercooled and glassy regimes of liquids. Using commonly employed methods to identify hops in real space, they are not evident at high temperatures (above TA), where relaxation follows an Arrhenius law, and are thus thought to be unimportant above this temperature. Employing reciprocal space analysis through the intermediate scattering function we not only identify excitations and hops above TA, we show that they are also a central relaxation and transport pathway in this high-temperature range.
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Publication: Cicerone, M. T. et al. arXiv preprint arXiv:2201.12593, 2022; <br> Cicerone, M. T. et al. Journal of Chemical Physics 146, (2017)<br>Cicerone et al. Physical Review Letters 113, 117801 (2014).
Presenters
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Marcus T Cicerone
Georgia Institute of Technology
Authors
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Marcus T Cicerone
Georgia Institute of Technology
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Jesse McDaniel
Georgia Institute of Technology