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Pressure-induced phase transitions in high entropy oxide and metal hydrides in DAC at over 100 GPa conditions

ORAL

Abstract

In this presentation, several selected crystalline systems were in situ studied under high pressure using synchrotron x-ray diffraction (XRD) technique in diamond anvil cell (DAC). Research topics involve phase transitions, isostructural transition, pressure tune charge transfer and mixed valance modifications behaviors, and negative linear compression at over 100 GPa conditions. One high entropy oxide system was used to investigate the compositions dependence of the phase transition sequence upon compression, and the fast compression rate effect was also studied. For many metal hydrides with the predicted superconducting properties, the responding superconducting phases determination are still quite challenging. Several selected cases such as Ca-H, Hf-H, would be presented based on the recent XRD results and discussed the possible general trend.

Publication: 1. Shuhua Yuan, Luhong Wang*, Sheng-cai Zhu, Fuyang Liu, Dongzhou Zhang, Vitali B. Prakapenka, Sergey Tkachev, Haozhe Liu*, Negative linear compressibility in Se at ultra-high pressure above 120 GPa, IUCrJ, 9, 253-260, 2022.<br>2. Zhiwen Li, Xin He, Changling Zhang, Xiancheng Wang*, Sijia Zhang, Yating Jia, Shaomin Feng, Ke Lu, Jianfa Zhao, Jun Zhang, Baosen Min, Youwen Long, Richeng Yu, Luhong Wang, Meiyan Ye, Zhanshuo Zhang, Vitali Prakapenka, Stella Chariton, Paul A. Ginsberg, Jay Bass, Shuhua Yuan, Haozhe Liu, Changqing Jin*, Superconductivity above 200 K discovered in superhydrides of calcium, Nature Communications, 13, 2863, 2022.<br>3. Changling Zhang, Xin He, Zhiwen Li, Sijia Zhang, Baosen Min, Jun Zhang, Ke Lu, Jianfa Zhao, Luchuan Shi, Yi Peng, Xiancheng Wang*, Shaomin Feng, Richeng Yu, Luhong Wang, Vitali B. Prakapenka, Stella Chariton, Haozhe Liu, Changqing Jin*, Superconductivity above 80 K in polyhydrides of hafnium, Materials Today Physics, 27, 100826, 2022. <br>4. Changling Zhang, Xin He, Chang Liu, Zhiwen Li, Ke Lu, Sijia Zhang, Shaomin Feng, Xiancheng Wang*, Yi Peng, Youwen Long, Richeng Yu, Luhong Wang, Vitali Prakapenka, Stella Chariton, Quan Li, Haozhe Liu, Changfeng Chen*, Changqing Jin*, Record high Tc element superconductivity achieved in titanium, Nature Communications, 13, 5411, 2022.

Presenters

  • Luhong Wang

    University of Illinois at Urbana Champaign, USA

Authors

  • Luhong Wang

    University of Illinois at Urbana Champaign, USA