Design & engineering of wood-inspired super-insulating foams
ORAL · Invited
Abstract
With the advent of the Green Economy, the use and valorization of lignocellulosic biomass as a possible alternative of fossil resources is a promising approach for elaborating low cost and high value-added insulation materials. Proper deconstruction or fractionation of cell wall components has indeed been reported to facilitate the development of a wide range of high value materials. The extraction of high aspect ratio cellulose nanomaterials (CNMs) or nanocelluloses, from e.g., wood cell walls, is especially creating a revolution in biobased materials for diverse applications such as packaging, cosmetics, automotive and electronics, owing to their low density, large surface area, and high strength-to-weight ratio.
I will present our latest research on heat transport of fully bio-based foams and their thermal response as a function of relative humidity. The deconstruction of wood cell wall into cellulose nanofibers (CNFs) lays the foundation for the production of high-performance bio-based foams. I will discuss two engineering approaches to manufacture super-insulating foams: 1- the influence of chemical surface modification of CNFs on heat transfer of subsequent foams, and 2- the nature-inspired assembly of unmodified CNFs with another wood-biopolymer namely lignin, for enhanced performance.
This presentation aims to share an insight on the potential of wood-based foams as thermal insulation materials, but also to inspire scientists, researchers, and future generations to exploit the biomass beyond traditional end-use products, such as for the engineering and manufacturing of sustainable advanced functional materials for energy transfer, storage, or conversion.
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Publication: Apostolopoulou-Kalkavoura, Varvara, Shiqian Hu, Nathalie Lavoine, Mohit Garg, Mathieu Linares, Pierre Munier, Igor Zozoulenko, Junichiro Shiomi, and Lennart Bergström. "Humidity-Dependent Thermal Boundary Conductance Controls Heat Transport of Super-Insulating Nanofibrillar Foams." Matter 4, no. 1 (2021): 276-289.<br><br>Lavoine, Nathalie, and Lennart Bergström. "Nanocellulose-based foams and aerogels: Processing, properties, and applications." Journal of Materials Chemistry A 5, no. 31 (2017): 16105-16117.<br><br>Trovagunta, Ramakrishna, Kelley, Stephen S and Lavoine, Nathalie. "A dual-templating approach for engineering strong, biodegradable lignin-based foams" Accepted for Publication in ACS Sustainable Chemistry and Engineering, (2022).
Presenters
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Nathalie Lavoine
NC State University
Authors
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Nathalie Lavoine
NC State University
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Varvara Aspotolopoulou-Kalkavoura
Stockholm University
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Shiqian Hu
Department of Mechanical Engineering, The University of Tokyo
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Mohit Garg
Laboratory of Organic Electronics, ITN, Linköping University
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Mathieu Linares
Laboratory of Organic Electronics, ITN, Linköping University
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Pierre Munier
Stockholm University
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Lennart Bergstrom
Stockholm University
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Igor Zozoulenko
Laboratory of Organic Electronics, ITN, Wallenberg Wood Science Center, Linköping University
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Junichiro Shiomi
Department of Mechanical Engineering, The University of Tokyo
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Stephen S Kelley
NC State University
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Ramakrishna Trovagunta
NC State University