Quantum Geometry of Light-Matter Interactions: New Approach to Multi-Band Physics

Geometry of quantum states has proved to be a useful concept for understanding responses of electronic systems to static electromagnetic fields. However, it has been challenging to relate quantum geometry with resonant optical responses. The main obstacle is that optical transitions are properties of a pair of states, while existing geometrical properties are defined for a single state. Therefore, concrete geometric understanding of optical responses has been limited to two-level systems, where one of two states determines the Hilbert space completely. Here, we construct a general theory of Riemannian geometry for resonant optical processes, by identifying transition dipole moment matrix elements as tangent vectors. This theory applies to arbitrarily high-order responses, suggesting that optical responses can be generally thought of as manifestations of the Riemannian geometry of quantum states. We use our theory to show that third-order photovoltaic Hall effects are related to the Riemann curvature tensor and demonstrate an experimentally accessible regime where they dominate the response. We discuss the implications of this theory to multiband physics in quantum materials.