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Elastic Fluctuations can drive Ferroelectric Transitions Incommensurate

ORAL

Abstract

We consider a Ginzburg-Landau theory for a ferroelectric phase transition whose primary order parameter (electrical polarization) is coupled to elastic strain through electrostriction. We show that the strain coupling leads to a quartic term in the effective Hamiltonian that describes long-range, anisotropic interactions between fluctuations in the order parameter. At the level of mean field theory plus Gaussian fluctuations, we demonstrate that the ferroelectric instability is driven to a finite wavevector, so that the transition from the disordered phase to the fully ordered ferroelectric phase must occur via an incommensurate phase.

Presenters

  • Charles H Liang

    University of Chicago

Authors

  • Charles H Liang

    University of Chicago

  • Gian G Guzmán-Verri

    Univ de Costa Rica, Universidad de Costa Rica

  • Peter B Littlewood

    University of Chicago