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Designer Potential Energy Surfaces via Magnetic Interactions

ORAL

Abstract

The potential energy surface (PES) describing the interactions between two or more atoms, molecules, or materials is a fundamental construct that can be used to predict the structures, properties, and dynamics of complex systems throughout biology, chemistry, physics, and materials science. In this work, we explore how patterned magnetostatic interactions can be used in the rational design of PES with targeted features. We first explore the PES design space that is accessible with small patterned magnetic arrays via forward and exhaustive enumeration, and characterize the resulting PES by the number, locations, and depths of the PES critical points. This is followed by a detailed investigation into the inverse problem—identification of magnetic patterns that correspond to PES with predefined features—using simulated annealing Monte Carlo (SA-MC) methods. In doing so, we demonstrate a robust theoretical and conceptual paradigm that enables forward and inverse PES engineering with precise control over the critical points and other salient surface features, thereby paving the way towards directed self-assembly using programmable magnetic interactions.

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Presenters

  • Robert Distasio

    Chemistry and Chemical Biology, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY

Authors

  • Yan Yang

    Chemistry and Chemical Biology, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Cornell University

  • Lijie Tu

    Chemistry and Chemical Biology, Cornell University

  • Yuchao Chen

    Physics, Cornell University, Massachusetts Institute of Technology, Cornell University

  • Dorothy Leung

    Chemistry and Chemical Biology, Cornell University

  • Ran Niu

    Physics Department, Cornell University, Physics, Cornell University, Cornell University

  • Hsin-Yu Ko

    Chemistry and Chemical Biology, Cornell University, Princeton University, Department of Chemistry and Chemical Biology, Cornell University, Cornell University

  • Yang Yang

    Chemistry and Chemical Biology, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY

  • Zachary Sparrow

    Chemistry and Chemical Biology, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Cornell University

  • Paul L McEuen

    Cornell University, Physics, Cornell University, Physics Department, Cornell University

  • Itai Cohen

    Cornell University, Physics, Cornell University, Physics Department, Cornell University, Department of Physics, Cornell University

  • Robert Distasio

    Chemistry and Chemical Biology, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Cornell University, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY