Tuning Fermi Levels in Intrinsic Antiferromagnetic Topological Insulators MnBi₂Te₄ and MnBi₄Te₇ by Defect Engineering and Chemical Doping

MnBi₂Te₄ and MnBi₄Te₇ are intrinsic antiferromagnetic topological insulators, offering a promising materials platform for realizing exotic topological quantum states. However, high densities of intrinsic defects in these materials not only cause bulk metallic conductivity, preventing the measurement of quantum transport in surface states, but may also affect magnetism and topological properties. Here, systematic density functional theory calculations reveal specific material chemistry and growth conditions that determine the defect formation and dopant incorporation in MnBi₂Te₄ and MnBi₄Te₇. The large strain induced by the internal heterostructure promotes the formation of large-size-mismatched antisite defects and substitutional dopants. Our results show that the abundance of antisite defects is responsible for the observed n-type metallic conductivity. We predict that a Te-rich growth condition should reduce the bulk free electron density, which is confirmed by experimental synthesis and transport measurements in MnBi₂Te₄. Furthermore, Na doping is proposed to be an effective acceptor dopant to pin the Fermi level within the bulk band gap to enable the observation of surface quantum transport.