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Unifying the percolation and mean-field description of the random Lorentz gas

ORAL

Abstract

The random Lorentz gas (RLG) is a minimal off-lattice model of transport in porous media. It is also a minimal model of structural glasses. The exact mean-field, infinite-dimensional limit solution of the RLG indeed predicts a discontinuous dynamical caging transition akin to that of simple liquid glass formers. The RLG, however, is also in the percolation universality class, in which the dynamical caging transition is continuous. These two descriptions are thus fundamentally contradictory. To resolve this paradox, we study the caging regime of the RLG as a function of dimension. We find that the static cage size quantitatively matches the mean-field predictions, and that the percolation transition and the (finite-dimensional echo of the) dynamical transition are clearly distinguishable in all dimensions. As dimension increases, however, the system dynamics grows increasingly controlled by the dynamical transition. In fact, the escape time from the dynamical cage grows exponentially quickly with d, thus resolving the paradox. More significantly, cage escape events are similar to hopping processes, which had mostly eluded theoretical description in standard supercooled liquids.

Presenters

  • Yi Hu

    Department of Chemistry, Duke University

Authors

  • Patrick Charbonneau

    Duke University, Department of Chemistry, Duke University

  • Eric Corwin

    Physics, University of Oregon, Univ of Oregon, Department of Physics, University of Oregon

  • Yi Hu

    Department of Chemistry, Duke University

  • Harukuni Ikeda

    Laboratoire de Physique, Ecole Normale Superieure

  • Francesco Zamponi

    Laboratoire de Physique de l’Ecole Normale Supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université de Paris, F-75005 Paris, France, Laboratoire de Physique, ENS Paris, Laboratoire de Physique, Ecole Normale Superieure