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Cluster Dynamic Mean Field Theory of Glass Transition

ORAL

Abstract

Recently, the infinite dimensional theory of the dynamics of super-cooled liquids was established in [1,2,3], and showed to be related to the mode coupling transition (MCT) theory [4]. One of the main mean field predictions is the existence of a sharp dynamical transition, akin to the MCT transition, at a temperature T_d, i.e. as the temperature approaches T_d from above, the relaxation time diverges. However, in three dimensional glass-formers this transition is smeared out and a smooth crossover takes place. We extend the infinite dimensional analysis by developing a cluster dynamic mean field theory (CDMFT) where clusters of particles interact in a mean field way, while correlations involving several particles are taken into account inside clusters. This allows us to progressively take into account correlations between particles and activated dynamical processes. In this talk we will present CDMFT and present results for three dimensional super-cooled liquids.

[1] Maimbourg.et.al Phys. Rev. Lett. 116 , 015902 (2016)
[2] G. Szamel Phys. Rev. Lett. 119, 15502 (2017)
[3] Agoritsas et al, J. Phys. A: Math. Theor. 52 144002 (2019)
[4] W. Götze, Complex dynamics of glass-forming liquids: A mode-coupling theory

Presenters

  • chen liu

    Physics, Ecole Normale Superieure

Authors

  • chen liu

    Physics, Ecole Normale Superieure

  • Giulio Biroli

    LPENS, Ecole Normale Superieure, Laboratoire de Physique, École normale supérieure, Ecole Normale Superieure, Physics, Ecole Normale Superieure

  • David Reichman

    Columbia University, Department of Chemistry, Columbia University

  • Grzegorz Szamel

    Colorado State University