\textbf{Magnetism in}\textbf{\textit{ Ln}}\textbf{MnSbO (}\textbf{\textit{Ln }} $=$\textbf{ La or Ce)}

ORAL

Abstract

Neutron diffraction of polycrystalline (PND) \textit{Ln}MnSbO (\textit{Ln }$=$ La or Ce) reveals differences between the magnetic ground state of the two compounds due to the strong Ce-Mn coupling compared to La-Mn. The two compounds adopt the \textit{P4/nmm} space group down to 1.5 K and whereas magnetization measurements do not show any anomaly at high temperatures, PND reveals a C-type antiferromagnetic (AFM) order below $T_{\mathrm{N}} \quad =$ 255 K for LaMnSbO and 240 K for CeMnSbO. While the magnetic structure of LaMnSbO is preserved to base temperature, a sharp transition at $T_{\mathrm{SR}} \quad =$ 5 K in CeMnSbO due to a spin-reorientation (SR) transition of the Mn$^{\mathrm{2+}}$ from pointing along the $c$-axis to the \textit{ab}-plane is found. The SR transition in CeMnSbO is accompanied by a simultaneous long-range AFM ordering of the Ce moments. This indicates that the Mn SR transition is driven by the Ce-Mn coupling similar to recent observation in the isostructural CeMnAsO. The ordered moments are found to be somewhat smaller than those expected for Mn$^{\mathrm{2+}}$ (S $=$ 5/2) in insulators, but large enough to suggest that these compounds belong to the class of local-moment antiferromagnets. The lower $T_{\mathrm{N\thinspace }}$found in this compound compared to the As-based counterpart ($T_{\mathrm{N}} \quad =$ 347K for CeMnAsO) indicates that the Mn-\textit{Pn} (\textit{Pn} $=$ As or Sb) hybridization that mediates the exchange Mn-Mn coupling is weaker for the Sb-based compounds.

Authors

  • Qiang Zhang

    Louisiana State Univ - Baton Rouge, Iowa State University

  • Naveen Kumar Chogondahalli M.

    Jülich Centre for Neutron Science

  • Kevin Dennis

    Iowa State University

  • Alan Goldman

    Ames Laboratory, U.S. DOE and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA, Ames Lab., Dept. of Physics and Astronomy, Iowa State Univ., Ames Laboratory, Dept. of Physics and Astronomy, Iowa State University, Ames Lab. & Iowa State Univ., Ames, IA, 50011, Iowa State University

  • David Vaknin

    Iowa State University, Ames Laboratory, Iowa State University