Collapse of the low temperature insulating state in Cr-doped V$_{2}$O$_{3}$ thin films

ORAL

Abstract

We have grown epitaxial Cr-doped V$_{2}$O$_{3}$ thin films with Cr concentrations between $0$ and $20$\% on ($0001$)-Al$_{2}$O$_{3}$ by oxygen-assisted molecular beam epitaxy. For the highly doped samples ($>$ $3$\%), a regular and monotonous increase of the resistance with decreasing temperature is measured. Strikingly, in the low doping samples (between $1$\% and $3$\%), a collapse of the insulating state is observed with a reduction of the low temperature resistivity by up to 5 orders of magnitude. A vacuum annealing at high temperature of the films recovers the low temperature insulating state for doping levels below $3$\% and increases the room temperature resistivity towards the values of Cr-doped V$_{2}$O$_{3}$ single crystals. It is well known that oxygen excess stabilizes a metallic state in V$_{2}$O$_{3}$ single crystals. Hence, we propose that Cr doping promotes oxygen excess in our films during deposition, leading to the collapse of the low temperature insulating state at low Cr concentrations. These results suggest that slightly Cr-doped V$_{2}$O$_{3}$ films can be interesting candidates for field effect devices.

Authors

  • Pia Homm

    KU Leuven

  • Leander Dillemans

    KU Leuven

  • Mariela Menghini

    KU Leuven

  • Bart Van Bilzen

    KU Leuven

  • Petar Bakalov

    Department of Solid-state physics, KULeuven, KU Leuven

  • Chen-Yi Su

    KU Leuven

  • Ruben Lieten

    KU Leuven

  • Michel Houssa

    KU Leuven

  • Jin Won Seo

    KU Leuven

  • Jean-Pierre Locquet

    KU Leuven

  • Davoud Nasr Esfahani

    University of Antwerp

  • Lucian Covani

    University of Antwerp

  • Francois Peeters

    University of Antwerp, Dept. of Physics, 2020 Antwerp, University of Antwerp