Utilizing Fiber-containing Thermo-responsive Gels to Extract Nanoparticles from Solution

Using computer simulations, we model an array of flexible fibers that are embedded in a lower critical solution temperature (LCST) thermo-responsive gel, which swells at lower temperatures and collapses at higher temperatures. The system is immersed in a solution containing dispersed nanoparticles and this fluid is driven to flow by an imposed shear. When the gel is heated, it collapses to expose the fibers, and thereby, triggers the ``catch'' process. Namely, the fibers can act like ``arms'' that wrap around the nanoparticle and bring it from the outer solvent into the gel layer. Moreover, we show that depending on the flexibility and hydrophobicity of the fibers, as well as the imposed shear, we can position the nanoparticles at the desired height within the gel layer. Our approach can be utilized for the detection and separation of components in fluids and for the controlled insertion of nanoparticles within a hydrogel at a particular distance from the gel interface