Optical Properties of LaVO$_3$ and YTiO$_3$

ORAL

Abstract

Motivated by recent experimental efforts to fabricate p-n junctions from transition metal oxides (TMOs) and recent theoretical and computational work illustrating that strongly correlated insulators can produce more than one electron-hole pair from a single solar photon through impact ionization, we study the optical properties of LaVO$_3$ and YTiO$_3$ by {\it ab initio} methods. We apply the Bethe-Salpeter equations (BSE) to calculate the optical properties, starting from quasi-particle energy levels and states found at the level of the GW approximation. We present comparisons of the exciton binding energy to experimental data. We examine the extent to which these materials might be promising for efficient carrier multiplication, as has been shown previously in VO$_2$.

Authors

  • John Coulter

    Florida State University, Florida State University \& NHMFL

  • Efstratios Manousakis

    Florida State University, Department of Physics, Florida State University and University of Athens, Florida State University \& NHMFL, Florida State Univ