Equilibrium-like phase transition of a dynamic system

ORAL

Abstract

Dynamic systems are considered to be intrinsically different from systems in thermal equilibrium. Despite this fundamental dichotomy, here we demonstrate that a non-equilibrium, fully dynamical system can display behavior that constitutes a complete analogy to thermal equilibrium phase behavior. This dynamical system, consisting of Janus colloids strongly controlled by external fields and over-damped by a viscous solvent, phase separates like a binary fluid mixture, with a coexistence curve separating mixed and demixed regimes and a critical point that we demonstrate to belong to the 2D Ising universality class. Within the coexistence curve, we locate the spinodal curve that separates spinodal decomposition from nucleation and growth.

Authors

  • Ming Han

    Northwestern University

  • Jing Yan

    University of Illinois at Urbana-Champaign

  • Steve Granick

    Univ of Illinois - Urbana, University of Illinois at Champaign-Urbana, University of Illinois, Urbana-Champaign, University of Illinois Urbana-Champaign, University of Illinois at Urbana-Champaign, Departments of Materials Science and Engineering, Chemistry, Physics, University of Illinois

  • Erik Luijten

    Northwestern University