Long-range plasmon-assisted energy transfer over doped graphene

ORAL

Abstract

F\"orster resonance energy transfer (FRET) between spatially separated donor and acceptor fluorophores, such as dye molecules or semiconductors quantum dots, underpins diverse phenomena in physics, chemistry and biology. However, the range of present and potential applications of FRET is limited by its intrinsically short-range nature ($\sim 1/R^6$). We demonstrate that longitudinal plasmons in doped monolayer graphene can mediate highly efficient long-range ($\sim 1/R$) energy transfer between nearby fluorophores, e.g., semiconductor quantum dots. We derive a simple analytical expression for the energy transfer efficiency that incorporates all the essential processes involved. We perform numerical calculations of the transfer efficiency for a pair of PbSe quantum dots near graphene for inter-fluorophore distances of up to 1 $\mu$m and find that the plasmon-assisted long-range energy transfer can be enhanced by up to a factor of $\sim 10^4$ relative to FRET in vacuum.

Authors

  • Kirill Velizhanin

    Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA

  • Tigran V. Shahbazyan

    Department of Physics, Jackson State University, Jackson, MS 39217, USA, Jackson State University