Convergence to Self-Similar Regimes in Thin Polymer Films

ORAL

Abstract

The surface of a thin liquid film with nonconstant curvature is unstable, as the Laplace pressure drives a flow mediated by viscosity. Recent experiments and theory applied to stepped polymer films have shown excellent agreement and provide a technique for the study of polymer confinement, the glass transition, and slip at the fluid substrate interface to name a few [1]. The thin film equation governs the evolution of the free surface profile in the lubrication approximation. Despite many efforts, this equation remains only partially solved. We present an analytical and numerical study of the thin film equation. Linearising this equation enables us to derive the Green's function of the problem and therefore obtain a complete set of solutions. We show that the solutions of the problem with equilibrium boundary conditions uniformly converge in time towards a first kind self-similar universal attractor. A numerical study enables us to extend our results to the nonlinear thin film equation.\\[4pt] [1] McGraw \textit{et al.} PRL \textbf {109} 128303 (2012).

Authors

  • Michael Benzaquen

    ESPCI

  • Thomas Salez

    ESPCI

  • Elie Rapha\"el

    Laboratoire de Physico-Chimie Theorique, UMR CNRS Gulliver 7083, ESPCI, Paris, France, ESPCI