Spin dynamics in the extended kagom\'{e} YBaCo$_{4}$O$_{7}$

ORAL

Abstract

The extended kagom\'{e} systemYBaCo$_{4}$O$_{7}$ consists of antiferromagnetically coupled Co$^{2+}$ and Co$^{3+}$ ions arranged in stacks with alternating kagom\'{e} and triangular layers in ab planes in the orthorhombic lattice. The oxygen-stoichiometric material orders below 110 K. The system exhibits interesting exchange topology with both trigonal bipyramids and triangular kagom\'{e} clusters of Co ions. Model calculations and neutron scattering experiments, made by other workers, have provided considerable information on the magnetic structure. Ordered chains are found for the apical ions along the c-axis with neighbor chains having oppositely directed polarizations perpendicular to c in an antiferromagnetic configuration. Only short range order is present in the kagom\'{e} planes at temperatures as low as 2 K. The present pulsed NMR measurements, made on a single crystal, both in zero magnetic field and in low applied fields, distinguish the Co ion sites and provide information on the evolution of the spin dynamics for the plane and chain sites as a function of temperature in the range 1.7 - 50 K above which signal wipe-out occurs. A dramatic change in the spin dynamics is found below 5 K.

Authors

  • Michael Hoch

    National High Magnetic Field Laboratory at Florida State University, Tallahassee, FL

  • Philip Kuhns

    National High Magnetic Field Laboratory at Florida State University, Tallahassee, FL

  • Tiglet Besara

    National High Magnetic Field Laboratory at Florida State University, Tallahassee, FL

  • A.P. Reyes

    National High Magnetic Field Laboratory, National High Magnetic Field Laboratory at Florida State University, Tallahassee, FL

  • John Mitchell

    Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA, Argonne National Laboratory, Argonne, IL, Argonne National Laboratory