Spatial Inhomogeneity in Oxygen Modulated Potassium Tungsten Oxide Thin Films: implications for superconductivity and metal-insulator transitions

High quality potassium tungsten oxide (K0.33 WOy) films were synthesized by pulsed laser deposition followed by annealing in vacuum. Oxygen concentration modulated anomalous correlation of metal-insulator and superconductivity transitions were studied; a similar scenario was recently suggested in the literature [1] for polycrystalline rubidium tungsten oxide samples. Detailed studies of the transport properties below and above the superconducting transition temperature exhibit a diversity of unexpected behavior. Some of our results can be interpreted as a signature of reduced dimensionality in the ab-plane in oxygen-rich insulating samples, implying a formation of spatially inhomogeneous electronic structure. We compare such phenomenology to the behavior of other materials with strong electron-phonon interactions, and discuss its implication for the possible high temperature superconducting anomaly in sodium tungsten oxides reported in the literature [2]. [1] D. C. Ling et. al., J. Phys. Conf. Ser. 150, 052141 (2009). [2] S. Reich, and Y. Tsabba, Eur. Phys. J. B 9, 1 (1999).