Quantifying and Minimizing Lattice Anisotropy

ORAL

Abstract

We have quantified the anisotropy of various lattice models used in polymer simulations based on two quantities: the Fourier transform of the normalized Boltzmann factor of allowable bonds on a lattice (which is the central quantity for describing lattice chain conformations), and the bulk lamellar period at the mean-field order-disorder transition of symmetric diblock copolymers on a lattice (which is pertinent to the study of microphase separation). This allowed us to compare the anisotropy of different lattices and to design new lattice models that minimize the quantified anisotropy.

Authors

  • Qiang WANG

    Department of Chemical and Biological Engineering, Colorado State University