Superconducting Fe-Based Compounds (A$_{1-x}$Sr$_{x })$Fe$_{2}$As$_{2}$ with A = K and Cs with Transition Temperatures up to 37 K

ORAL

Abstract

New high-Tc Fe-based superconducting compounds, AFe$_{2}$As$_{2}$ with A = K, Cs, K/Sr, and Cs/Sr, were synthesized. The Tc of KFe$_{2}$As$_{2}$ and CsFe$_{2}$As$_{2}$ is 3.8 and 2.6 K, respectively, which rises with partial substitution of Sr for K and Cs and peaks at 37 K for 50{\%}--60{\%} Sr substitution, and the compounds enter a spin-density-wave state with increasing electron number (Sr content). The compounds represent p-type analogs of the n-doped rare-earth oxypnictide superconductors. Their electronic and structural behavior demonstrate the crucial role of the (Fe$_{2}$As$_{2})$ layers in the superconductivity of the Fe-based layered systems, and the special feature of having elemental A layers provides new avenues to superconductivity at higher Tc.

Authors

  • Kalyan Sasmal

    TCSUH and Department of Physics, University of Houston, Houston, Texas 77204, USA

  • Bing Lv

    Texas Center for Superconductivity at the University of Houston and Department of Chemistry, TCSUH and Department of Chemistry, University of Houston, Houston, Texas 77204, USA

  • Bernd Lorenz

    TCSUH and Department of Physics, University of Houston, Houston, Texas 77204-5002, USA, TCSUH and Dept. of Physics, University of Houston, Texas Center for Superconductivity at the University of Houston and Department of Physics, TCSUH and Department of Physics, University of Houston, Houston, Texas 77204, USA

  • Arnold M. Guloy

    Dept. of Chemistry, University of Houston, Houston, TX 77204, Texas Center for Superconductivity at the University of Houston and Department of Chemistry, TCSUH and Department of Chemistry, University of Houston, Houston, Texas 77204, USA

  • Feng Chen

    TCSUH and Department of Physics, University of Houston, Houston, Texas 77204, USA

  • Yu-Yi Xue

    University of Houston, TCSUH and Department of Physics, University of Houston, Houston, Texas 77204, USA

  • Ching-Wu Chu

    University of Houston, TCSUH and Department of Physics, University of Houston, Houston, Texas 77204-5002, USA, Dept. of Physics and Texas Center for Superconductivity, University of Houston, Houston, TX 77204-5002, Texas Center for Superconductivity at the University of Houston; Lawrence Berkeley National Laboratory; Hong Kong University of Science and Technology, TCSUH and Department of Physics, University of Houston, Houston, Texas 77204, USA;