Ferromagnetic multipods fabricated by solution phase synthesis and hydrogen reduction

ORAL

Abstract

New functional materials might emerge if nanocrystals of higher complexity than those with simple geometries (spheres, rod, discs) could be produced. Branched nanostructures (called multipods) have attracted much attention owing to their potential as building blocks in the fabrication of complex, multi-terminal devices through self assembly. In this work, we demonstrate that ferromagnetic Co multi-branched nanostructures can be produced through the combination of solution-phase synthesis and hydrogen reduction. The CoO multipods were produced through the pyrolysis of cobalt-oleate in octadecane at 280$^{o}$C in the presence of oleic acid under the protection of pure nitrogen. Arm lengths and diameters of the CoO multipods are about 30 and 10 nm respectively, and the angles between the nearest arms are 90 degrees. The multipods were assembled onto Si substrates, and after reduction in flowing hydrogen gas at 290$^{o}$C, pure cobalt with hexagonal crystal structure and multi-branched structures were created. Anisotropic magnetic properties were found for cobalt multipods. The growth mechanism of CoO multipods will be presented in this work.

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Authors

  • Yucheng Sui

    Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, NE, 68588-0111, USA, Department of Physics and Astronomy and NCMN, University of Nebraska, Lincoln, NE, 68588-0113, Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, Nebraska 68588-0111, Department of Physics and Astronomy, University of Nebraska-Lincoln, Lincoln, NE 68588 USA

  • Yao Zhao

    Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, NE, 68588-0111, USA, Department of Physics and Astronomy and NCMN, University of Nebraska, Lincoln, NE, 68588-0113

  • Jun Zhang

    Department of Physics and Astronomy and NCMN, University of Nebraska, Lincoln, NE, 68588-0113

  • Sitaram Jaswal

    Department of Physics and Astronomy and NCMN, University of Nebraska, Lincoln, NE, 68588-0113

  • Xingzhong Li

    Department of Physics and Astronomy and NCMN, University of Nebraska, Lincoln, NE, 68588-0113

  • D.J. Sellmyer

    Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, NE, 68588-0111, USA, Department of Physics and Astronomy and NCMN, University of Nebraska, Lincoln, NE, 68588-0113, Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience, University of Nebraska-Lincoln, USA