Growth of vertically aligned multiwall and uniform carbon nanotubes on self-assembled ferromagnetic Fe and Co nanowires
ORAL
Abstract
A novel approach to grow vertically aligned and uniformly separated carbon nanotubes on self-assembled \textit{$\alpha $}-Fe is reported. We have previously demonstrated that the growth of LaSrFeO$_{3}$ perovskite oxide by Pulsed Laser Deposition under reducing environments leads to spontaneous formation of an array of single crystalline \textit{$\alpha $}-Fe nanowires embedded in an antiferromagnetic LaSrFeO$_{4}$ matrix. The diameter and spacing of these ferromagnetic nanowires can be controlled by changing the temperature of growth. We now show that these thin films containing self-assembled $\alpha $-Fe nanowires can be used as a template to grow vertically aligned carbon nanotubes using Plasma Enhanced Chemical Vapor Deposition. Acetylene (C$_{2}$H$_{2})$ and ammonia (NH$_{3})$ were used as a carbon source and diluting gas, respectively. Self-assembled \textit{$\alpha $}-Fe nanowires serve as a nucleation sites for the growth of vertically aligned multiwall carbon nanotubes (MWCNTs). The size of carbon nanotubes can be controlled by changing the diameter of \textit{$\alpha $}-Fe nanowires. The results of Transmission Electron Microscopy, Raman spectroscopy and field emission data will be presented. By means chemical mechanical polishing we can achieve atomically smooth surfaces and improve the quality of the carbon nanotubes grown on these nanowires.
–
Authors
-
L. Mohaddes-Ardabili
Univ of Maryland and U C Berkeley, U C Berkeley
-
S.Y. Yang
Dept. of Materials Science, Univ. of Maryland, College Park MD 20742
-
J.H. Han
-
J.B. Yoo
-
Ramamoorthy Ramesh
Dept. of Materials Science and Engineering, and Dept. of Physics, Univ. of California, Berkeley CA 94720, Dept of Materials Science and Physics, University of California, Berkeley CA 94720, Univeristy of California, Berkeley, U C Berkeley, University of California, Berkeley