On the singular limit of three-phase contact lines in a ternary Cahn-Hilliard model

ORAL

Abstract

We investigate the physically relevant singular limit of a thermodynamically-consistent model of ternary liquid-liquid phase separation. The emergence of three-phase contact lines significantly complicates the analysis. We combine three techniques to purse this analysis to arbitrary asymptotic order: 1. Physically meaningful and geometrically elegant coordinate systems adapted to each subproblem. 2. A comprehensive symbolic algebra system for performing and validating the analysis. 3. Little-known identities for complete analytic solutions to the codimension-1 spectral subproblem. We also discuss the algorithms needed for accurate numerical validation of these models, and explore the applications of these simplified models to microfluidic manufacture of Janus droplets.

Publication: Planned paper:
On the contact line dynamics of three-phase fluids

Pursues theoretical analysis of previously published work:
Hester, Eric W., Sean Carney, Vishwesh Shah, Alyssa Arnheim, Bena Patel, Dino Di Carlo, and Andrea L. Bertozzi. "Fluid Dynamics Alters Liquid–Liquid Phase Separation in Confined Aqueous Two-Phase Systems." Proceedings of the National Academy of Sciences 120, no. 49 (December 5, 2023): e2306467120. https://doi.org/10.1073/pnas.2306467120.

Presenters

  • Eric W Hester

    University of Bath

Authors

  • Eric W Hester

    University of Bath