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Reactive mixing in a shear flow

ORAL

Abstract

We investigate the interaction between chemical reaction and diffusion on a moving substrate and by means of an original chemical reaction between two transparent reactants (fluorescin and potassium ferricyanide) which produce a fluorescent product in water (fluorescein) with tunable kinetics. A blob of fluorescin in a cell filled with potassium ferricyanide is advected in a simple shear flow. The blob deforms into an elongated strip diffusing from its borders at a shear-dependent rate. Depending on the ratio of the mixing time to the reaction time (Damkh\"oler number $Da$), several regimes are identified: When $Da>1$, the product concentration remains constant in the reaction zones until the reactive borders overlap, while when $Da<1$ the product concentration increases linearly in time at a rate controlled by the reaction only. The mixing-controlled decay rate of the final product concentration after the reaction is completed is described as well.

Authors

  • Emilie Guilbert

    Aix Marseille University

  • Christophe Almarcha

    Aix Marseille University, Aix Marseille Université, CNRS, Centrale Marseille, IRPHE UMR 7342, 13384 Marseille, France

  • Henri Lhuissier

    Aix-Marseille University, IUSTI-CNRS UMR 7343, 13453 Marseille, France, CNRS, IUSTI CNRS UMR 7343 Marseille France

  • Bloen metzger

    Aix-Marseille University, IUSTI-CNRS UMR 7343, 13453 Marseille, France, CNRS, IUSTI CNRS UMR 7343 Marseille France

  • Emmanuel Villermaux

    Aix Marseille University