Reduced model for multi-component condensation

ORAL

Abstract

An extremely efficient reduced model for multi-component condensation is presented. The Becker-D\"oring (BD) equations are approximated by the General Dynamic Equation (GDE) in the supercritical region. The subcritical and critical regions are replaced by a source point that injects clusters into the supercritical region. The location and strength of the source point are determined from local estimates of the Gibbs free energy function, and the diffusion term in a corresponding Fokker-Planck equation. The result is a curve in composition space with Dirac delta function character in planes perpendicular to the curve. Integral properties of the GDE and BD solutions compare well for a typical two-component nucleation pulse experiment and computational effort is reduced by five orders of magnitude.

Authors

  • Dennis van Putten

    University of Twente

  • Rob Hagmeijer

    University of Twente

  • Ryan Sidin

    University of Suriname