Stabilization of ion concentration polarization using a heterogeneous nanoporous junction

ORAL

Abstract

We demonstrate a recycled ion -- flux through heterogeneous nanoporous junctions, which induce stable ion concentration polarization (ICP) with an electric field. The nanoporous junctions are based on integration of ionic hydrogels whose surfaces are negatively- and positively- charged for cationic selectivity and anionic selectivity, respectively. It is shown that a `heterojunction' structure with cationic selective hydrogels (CSH) and anionic selective hydrogels (ASH) can be matched up in a way to achieve continuous ion-flux operation for stable concentration gradient or ionic conductance. Furthermore, the combined junctions can be used to accumulate ions on a specific region of the device.

Authors

  • Pilnam Kim

    Seoul National University

  • Sung Jae Kim

    Massachusetts Institute of Technology

  • Jongyoon Han

    Massachusetts Institute of Technology, MIT

  • Kahp Y. Suh

    Seoul National University