Is a randomly stirred mixture a maximum entropy object?
ORAL
Abstract
A randomly stirred scalar mixture can be viewed as a set of adjacent stretched sheets, merging diffusively into each other. For a mixture decaying at fixed stirring intensity and average concentration, the consequences of this vision offer a precise description of the shape and evolution of the concentration Probability Density Function [PRL 91 (18), 184501, (2003)]. Because of the aggregation between nearby sheets, the concentration field is defined on a naturally coarse grained scale $\eta$ incorporating many independent merged sheets. There is obviously a number of ways to realize a given macroscopic concentration distribution by assembling elementary sheets into independent boxes of size $\eta$. From the inventory of the number of microscopic states, we derive the corresponding entropy, and show that real mixtures {\it do~not} maximize entropy. Real and maximum entropy distributions are however close in shape and evolution, and both consistently lead to the same value of the entropy at complete mixing.
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Authors
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Emmanuel Villermaux
IRPH\'E, Marseille
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J\'er\^ome Duplat
IUSTI, Marseille