Band folding of the image potential states at the phthalocyanine/Ag interface

ORAL

Abstract

Two-photon photoemission is used to probe image potential states at the metal-molecule interface. We compare model systems of monolayer metal-free phthalocyanine and cobalt phthalocyanine adsorbed on Ag(100) and Ag(111). Both phthalocyanines show very similar image state binding energies and dispersions. Strikingly, the spectra clearly show the opening of a band gap in the first image potential state, regardless of the presence of the electron dense metal center. Experiments conducted on both Ag(100) and Ag(111) determined the role of the surface symmetry and projected bulk band structure. Our results are contrasted to the PTCDA/Ag(100) interface. Finally, we compare to experiments a model that takes into account both the band structure of the substrate and the phthalocyanine induced corrugation of the potential energy landscape.

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Authors

  • Benjamin Caplins

    University of California, Berkeley -- Dept of Chemistry

  • Sergey Savrasov

    Hartnell College, Cal State Univ- Long Beach, University of California, Davis, School of Natural Science, University of California, Merced, Seagate Technology, Materials Science and Engineering, National Tsing Hua University, Taiwan, University of California - Berkeley, University of Colorado, Boulder -- Dept of Physics, University of California, Berkeley -- Dept of Chemistry, UC Merced, California State University, Fresno, California Institute of Technology, California State University, Long Beach, La Canada Flintridge, CA, Department of Physics, Florida A\&M University, Tallahassee, FL-32307, Physical and Life Sciences, Lawrence Livermore National Laboratory, Livermore, CA-94550, Cal State Univ East Bay, American River College, UC Santa Cruz, Notre Dame High School, Benedict College, Lawrence Livermore National Laboratory, Tuskegee University, California State University, Dominguez Hills, Sonoma State University, Carnegie Observatories, University of California, Los Angeles, Institute of Astronomy, University of Cambridge, UK, University of California, Santa Barbara, University of Alabama, MPIfR, Bonn, Germany, Stanford University, University of California - Davis

  • Sergey Savrasov

    Hartnell College, Cal State Univ- Long Beach, University of California, Davis, School of Natural Science, University of California, Merced, Seagate Technology, Materials Science and Engineering, National Tsing Hua University, Taiwan, University of California - Berkeley, University of Colorado, Boulder -- Dept of Physics, University of California, Berkeley -- Dept of Chemistry, UC Merced, California State University, Fresno, California Institute of Technology, California State University, Long Beach, La Canada Flintridge, CA, Department of Physics, Florida A\&M University, Tallahassee, FL-32307, Physical and Life Sciences, Lawrence Livermore National Laboratory, Livermore, CA-94550, Cal State Univ East Bay, American River College, UC Santa Cruz, Notre Dame High School, Benedict College, Lawrence Livermore National Laboratory, Tuskegee University, California State University, Dominguez Hills, Sonoma State University, Carnegie Observatories, University of California, Los Angeles, Institute of Astronomy, University of Cambridge, UK, University of California, Santa Barbara, University of Alabama, MPIfR, Bonn, Germany, Stanford University, University of California - Davis

  • Sergey Savrasov

    Hartnell College, Cal State Univ- Long Beach, University of California, Davis, School of Natural Science, University of California, Merced, Seagate Technology, Materials Science and Engineering, National Tsing Hua University, Taiwan, University of California - Berkeley, University of Colorado, Boulder -- Dept of Physics, University of California, Berkeley -- Dept of Chemistry, UC Merced, California State University, Fresno, California Institute of Technology, California State University, Long Beach, La Canada Flintridge, CA, Department of Physics, Florida A\&M University, Tallahassee, FL-32307, Physical and Life Sciences, Lawrence Livermore National Laboratory, Livermore, CA-94550, Cal State Univ East Bay, American River College, UC Santa Cruz, Notre Dame High School, Benedict College, Lawrence Livermore National Laboratory, Tuskegee University, California State University, Dominguez Hills, Sonoma State University, Carnegie Observatories, University of California, Los Angeles, Institute of Astronomy, University of Cambridge, UK, University of California, Santa Barbara, University of Alabama, MPIfR, Bonn, Germany, Stanford University, University of California - Davis

  • Charles Harris

    University of California, Berkeley -- Dept of Chemistry