Probing thermal decomposition of Ni$_{\mathrm{3}}^{\mathrm{+2}}$[Fe$^{\mathrm{3+}}$(CN)$_{\mathrm{6}}$]$_{\mathrm{2}}$.nH$_{\mathrm{2}}$O

ORAL

Abstract

The Prussian Blue Analogue (PBA), Ni$_{\mathrm{3}}^{\mathrm{+2}}$[Fe$^{\mathrm{3+}}$(CN)$_{\mathrm{6}}$]$_{\mathrm{2}}$.nH$_{\mathrm{2}}$O, has a framework structure with alternating C$_{\mathrm{6}}$ and N$_{\mathrm{6}}$ octahedra with the transitional metals at the octahedral centers and connected with rigid $C-N $bonds. The water molecules are located either in the framework between octahedra or on C or N defect sites. Thermal decomposition PBA is commonly inferred from the Thermogravimetric Analysis (TGA) by considering the mass loss is due to the loss of water molecules, while the framework structure remains the same. We had performed DFT calculations, and it indicates a different decomposition mechanism. To probe the decomposition, we prepared a deuterized sample as D has higher coherent scattering length than H. We performed powder neutron diffraction at different temperatures between room temperature and 600$^{\mathrm{0}}$C. We used Rietveld refinement on the average structure and pair distribution function analysis on the local structure. Our analysis shows that at elevated temperature the framework structure is distorted, and certain bond vanishes.

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Authors

  • Md Minuddin

    New Mexico State University

  • Rupjyoti Gogoi

    Arizona State University, Colorado State University, University of Utah, Utah State University, George Mason University, Brigham Young University, University of Colorado, Boulder, Georgia Institute of Technology, University of Colorado, Boulder; North China Electric Power University, Argonne National Laboratory, Carnegie Mellon University, Purdue University, Yunnan University, University of Arizona, Ball Aerospace, Ponderosa Associates Limited, Polsinelli PC, Saleh Research Centre, New Mexico State University, Oak Ridge National Laboratory, Center for Memory and Recording research, Advanced Photon Source, Chemnitz university of technology, Tezpur University

  • Rupjyoti Gogoi

    Arizona State University, Colorado State University, University of Utah, Utah State University, George Mason University, Brigham Young University, University of Colorado, Boulder, Georgia Institute of Technology, University of Colorado, Boulder; North China Electric Power University, Argonne National Laboratory, Carnegie Mellon University, Purdue University, Yunnan University, University of Arizona, Ball Aerospace, Ponderosa Associates Limited, Polsinelli PC, Saleh Research Centre, New Mexico State University, Oak Ridge National Laboratory, Center for Memory and Recording research, Advanced Photon Source, Chemnitz university of technology, Tezpur University

  • Rupjyoti Gogoi

    Arizona State University, Colorado State University, University of Utah, Utah State University, George Mason University, Brigham Young University, University of Colorado, Boulder, Georgia Institute of Technology, University of Colorado, Boulder; North China Electric Power University, Argonne National Laboratory, Carnegie Mellon University, Purdue University, Yunnan University, University of Arizona, Ball Aerospace, Ponderosa Associates Limited, Polsinelli PC, Saleh Research Centre, New Mexico State University, Oak Ridge National Laboratory, Center for Memory and Recording research, Advanced Photon Source, Chemnitz university of technology, Tezpur University

  • Heinz Nakotte

    New Mexico State University