Magnetic properties of 3d-metal Prussian Blue Analogs

ORAL

Abstract

Prussian Blue Analogs consists of MC$_{6}$ and AN$_{6}$ octahedra connected by cyanide ligands (M, A$=$ metals). They typically crystallize in cubic structures. We have studied temperature and field dependence of the magnetization and the susceptibility of 3d-metal Prussian Blue Analogs, namely the hexacyanocobaltates, -ferrates and -chromates. All compounds exhibit modified Curie --Weiss behavior in the paramagnetic region. The observed effective moments of those compounds were compared with the ones of the respective free-ion values. Furthermore, we find evidence that a few of the compounds exhibit a transition to long-range magnetic order at low temperatures.

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Authors

  • Manjita Shrestha

    New Mexico State University

  • Norm Buchanan

    Brigham Young University, Stanford University, University of Central Florida, NCAR/High Altitude Observatory, Arizona Vitro-retinal consultants, University of Michigan, Arizona State University, University of Denver, Arizona State University Dept of Physics, Arizona State University Dept of Chemistry and Biochemistry, LASP, University of Colorado Boulder, Center for Atmospheric and Space Science, Utah State University, Dixie State College, Utah, USU Materials Physics Group, UVU Physics Department, Box Elder Innovations, Space Telescope Science Institute, Northern Kentucky University, Retired, Utah Valley University, Univ. of California, Los Angelos, Colorado State University, St. Petersburg Electro-technical University, Universidad Nacional Aut\'onoma de M\'exico, New Mexico State University, University of New Mexico, University of Wurtzberg, Theoretical Division, Los Alamos National Laboratory, National High Magnetic Field Laboratory, LANL, UCLA, Max-planck-Institut f\"{u}r Astronomie, W. M. Keck Observatory, University of Arizona, Nuclear Physics Group, Brigham Young University, GLOBALFOUNDRIES, IBM Systems and Technology Group, IBM Research Division, T.J. Watson Research Center, Sandia National Laboratory, NMSU, Military University of Technology, Warsaw, Poland, James Franck Institute and Department of Physics, University of Chicago, Department of Atmospheric Sciences, University of Washington, JISAO, University of Washington, New Mexico Institute of Mining and Technology, NorthWest Research Associates, University of Alaska, Fairbanks, Utah State University, New Mexico Tech, University of Cambridge, Los Alamos National Laboratory, RAPTOR Science, Institute of Space and Astronomical Science, Japanese Aerospace Exploration Agency, Weber State University, Department of Physics, New Mexico State University, BYU Physics, Physics Department, University of Arizona, ABQMR, University of Colorado at Boulder, SNL and CINT, Los Alamos National Lab, Center for Quantum Information and Control, University of Arizona, Center for Quantum Information and Control, University of New Mexico, University of Calgary, Colorado School of Mines

  • Norm Buchanan

    Brigham Young University, Stanford University, University of Central Florida, NCAR/High Altitude Observatory, Arizona Vitro-retinal consultants, University of Michigan, Arizona State University, University of Denver, Arizona State University Dept of Physics, Arizona State University Dept of Chemistry and Biochemistry, LASP, University of Colorado Boulder, Center for Atmospheric and Space Science, Utah State University, Dixie State College, Utah, USU Materials Physics Group, UVU Physics Department, Box Elder Innovations, Space Telescope Science Institute, Northern Kentucky University, Retired, Utah Valley University, Univ. of California, Los Angelos, Colorado State University, St. Petersburg Electro-technical University, Universidad Nacional Aut\'onoma de M\'exico, New Mexico State University, University of New Mexico, University of Wurtzberg, Theoretical Division, Los Alamos National Laboratory, National High Magnetic Field Laboratory, LANL, UCLA, Max-planck-Institut f\"{u}r Astronomie, W. M. Keck Observatory, University of Arizona, Nuclear Physics Group, Brigham Young University, GLOBALFOUNDRIES, IBM Systems and Technology Group, IBM Research Division, T.J. Watson Research Center, Sandia National Laboratory, NMSU, Military University of Technology, Warsaw, Poland, James Franck Institute and Department of Physics, University of Chicago, Department of Atmospheric Sciences, University of Washington, JISAO, University of Washington, New Mexico Institute of Mining and Technology, NorthWest Research Associates, University of Alaska, Fairbanks, Utah State University, New Mexico Tech, University of Cambridge, Los Alamos National Laboratory, RAPTOR Science, Institute of Space and Astronomical Science, Japanese Aerospace Exploration Agency, Weber State University, Department of Physics, New Mexico State University, BYU Physics, Physics Department, University of Arizona, ABQMR, University of Colorado at Boulder, SNL and CINT, Los Alamos National Lab, Center for Quantum Information and Control, University of Arizona, Center for Quantum Information and Control, University of New Mexico, University of Calgary, Colorado School of Mines

  • Norm Buchanan

    Brigham Young University, Stanford University, University of Central Florida, NCAR/High Altitude Observatory, Arizona Vitro-retinal consultants, University of Michigan, Arizona State University, University of Denver, Arizona State University Dept of Physics, Arizona State University Dept of Chemistry and Biochemistry, LASP, University of Colorado Boulder, Center for Atmospheric and Space Science, Utah State University, Dixie State College, Utah, USU Materials Physics Group, UVU Physics Department, Box Elder Innovations, Space Telescope Science Institute, Northern Kentucky University, Retired, Utah Valley University, Univ. of California, Los Angelos, Colorado State University, St. Petersburg Electro-technical University, Universidad Nacional Aut\'onoma de M\'exico, New Mexico State University, University of New Mexico, University of Wurtzberg, Theoretical Division, Los Alamos National Laboratory, National High Magnetic Field Laboratory, LANL, UCLA, Max-planck-Institut f\"{u}r Astronomie, W. M. Keck Observatory, University of Arizona, Nuclear Physics Group, Brigham Young University, GLOBALFOUNDRIES, IBM Systems and Technology Group, IBM Research Division, T.J. Watson Research Center, Sandia National Laboratory, NMSU, Military University of Technology, Warsaw, Poland, James Franck Institute and Department of Physics, University of Chicago, Department of Atmospheric Sciences, University of Washington, JISAO, University of Washington, New Mexico Institute of Mining and Technology, NorthWest Research Associates, University of Alaska, Fairbanks, Utah State University, New Mexico Tech, University of Cambridge, Los Alamos National Laboratory, RAPTOR Science, Institute of Space and Astronomical Science, Japanese Aerospace Exploration Agency, Weber State University, Department of Physics, New Mexico State University, BYU Physics, Physics Department, University of Arizona, ABQMR, University of Colorado at Boulder, SNL and CINT, Los Alamos National Lab, Center for Quantum Information and Control, University of Arizona, Center for Quantum Information and Control, University of New Mexico, University of Calgary, Colorado School of Mines

  • Norm Buchanan

    Brigham Young University, Stanford University, University of Central Florida, NCAR/High Altitude Observatory, Arizona Vitro-retinal consultants, University of Michigan, Arizona State University, University of Denver, Arizona State University Dept of Physics, Arizona State University Dept of Chemistry and Biochemistry, LASP, University of Colorado Boulder, Center for Atmospheric and Space Science, Utah State University, Dixie State College, Utah, USU Materials Physics Group, UVU Physics Department, Box Elder Innovations, Space Telescope Science Institute, Northern Kentucky University, Retired, Utah Valley University, Univ. of California, Los Angelos, Colorado State University, St. Petersburg Electro-technical University, Universidad Nacional Aut\'onoma de M\'exico, New Mexico State University, University of New Mexico, University of Wurtzberg, Theoretical Division, Los Alamos National Laboratory, National High Magnetic Field Laboratory, LANL, UCLA, Max-planck-Institut f\"{u}r Astronomie, W. M. Keck Observatory, University of Arizona, Nuclear Physics Group, Brigham Young University, GLOBALFOUNDRIES, IBM Systems and Technology Group, IBM Research Division, T.J. Watson Research Center, Sandia National Laboratory, NMSU, Military University of Technology, Warsaw, Poland, James Franck Institute and Department of Physics, University of Chicago, Department of Atmospheric Sciences, University of Washington, JISAO, University of Washington, New Mexico Institute of Mining and Technology, NorthWest Research Associates, University of Alaska, Fairbanks, Utah State University, New Mexico Tech, University of Cambridge, Los Alamos National Laboratory, RAPTOR Science, Institute of Space and Astronomical Science, Japanese Aerospace Exploration Agency, Weber State University, Department of Physics, New Mexico State University, BYU Physics, Physics Department, University of Arizona, ABQMR, University of Colorado at Boulder, SNL and CINT, Los Alamos National Lab, Center for Quantum Information and Control, University of Arizona, Center for Quantum Information and Control, University of New Mexico, University of Calgary, Colorado School of Mines

  • Norm Buchanan

    Brigham Young University, Stanford University, University of Central Florida, NCAR/High Altitude Observatory, Arizona Vitro-retinal consultants, University of Michigan, Arizona State University, University of Denver, Arizona State University Dept of Physics, Arizona State University Dept of Chemistry and Biochemistry, LASP, University of Colorado Boulder, Center for Atmospheric and Space Science, Utah State University, Dixie State College, Utah, USU Materials Physics Group, UVU Physics Department, Box Elder Innovations, Space Telescope Science Institute, Northern Kentucky University, Retired, Utah Valley University, Univ. of California, Los Angelos, Colorado State University, St. Petersburg Electro-technical University, Universidad Nacional Aut\'onoma de M\'exico, New Mexico State University, University of New Mexico, University of Wurtzberg, Theoretical Division, Los Alamos National Laboratory, National High Magnetic Field Laboratory, LANL, UCLA, Max-planck-Institut f\"{u}r Astronomie, W. M. Keck Observatory, University of Arizona, Nuclear Physics Group, Brigham Young University, GLOBALFOUNDRIES, IBM Systems and Technology Group, IBM Research Division, T.J. Watson Research Center, Sandia National Laboratory, NMSU, Military University of Technology, Warsaw, Poland, James Franck Institute and Department of Physics, University of Chicago, Department of Atmospheric Sciences, University of Washington, JISAO, University of Washington, New Mexico Institute of Mining and Technology, NorthWest Research Associates, University of Alaska, Fairbanks, Utah State University, New Mexico Tech, University of Cambridge, Los Alamos National Laboratory, RAPTOR Science, Institute of Space and Astronomical Science, Japanese Aerospace Exploration Agency, Weber State University, Department of Physics, New Mexico State University, BYU Physics, Physics Department, University of Arizona, ABQMR, University of Colorado at Boulder, SNL and CINT, Los Alamos National Lab, Center for Quantum Information and Control, University of Arizona, Center for Quantum Information and Control, University of New Mexico, University of Calgary, Colorado School of Mines