High-pressure Raman studies of both hcp phases of Ba.

ORAL

Abstract

Both hcp high-pressure phases of Ba were sudied by Raman spectroscopy. Combining the Raman data with existing equation of state data, the pressure dependence of the elastic shear modulus $C_{44} $ has been derived. The pressure shift of the E$_{2g}$ phonon frequency is discussed in terms of elastic parameters. Though the pressure response of the observed phonon mode shows normal behaviour in both phases, more subtle differences can be traced back to differences in the interatomic interactions in both phases.

Authors

  • Helmut Olijnyk

    Department of Physics, Colorado State University, Fort Collins, CO 80523, USA

  • Stanley C. Solomon

    University of California and Lawrence Berkeley National Laboratory, Rutgers University, Utah State University, Brigham Young University, University of Utah, NASA, Duke University, FMA Research, Colorado State University, Dartmouth University, Idaho State University, Physics Department, Idaho State University, Physics Department, Utah State University, Los Alamos National Laboratory, Department of Physics, Nanjing University, China, University of California at Riverside, Physics Department, Colorado School of Mines, Physics Department, University of Utah, University of Nebraska - Lincoln, USU, Society of Physics Students, Arizona State University, Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan, LANSCE-LC, Los Alamos National Laboratory, Van der Waals-Zeeman Institute, University of Amsterdam, Chemistry and Physics Dept., Virginia State University, University of Saskatchewan, Canada, Chalk River Laboratories, Physics Dept, Oxford University, Physics Dept, Utah State University, Sandia National Laboratories, National Renewable Energy Laboratory, DOE Center for Integrated Nanotechnologies, Sandia National Laboratories, National Center for Atmospheric Research

  • Stanley C. Solomon

    University of California and Lawrence Berkeley National Laboratory, Rutgers University, Utah State University, Brigham Young University, University of Utah, NASA, Duke University, FMA Research, Colorado State University, Dartmouth University, Idaho State University, Physics Department, Idaho State University, Physics Department, Utah State University, Los Alamos National Laboratory, Department of Physics, Nanjing University, China, University of California at Riverside, Physics Department, Colorado School of Mines, Physics Department, University of Utah, University of Nebraska - Lincoln, USU, Society of Physics Students, Arizona State University, Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan, LANSCE-LC, Los Alamos National Laboratory, Van der Waals-Zeeman Institute, University of Amsterdam, Chemistry and Physics Dept., Virginia State University, University of Saskatchewan, Canada, Chalk River Laboratories, Physics Dept, Oxford University, Physics Dept, Utah State University, Sandia National Laboratories, National Renewable Energy Laboratory, DOE Center for Integrated Nanotechnologies, Sandia National Laboratories, National Center for Atmospheric Research